Preview

Lomonosov Geography Journal

Advanced search

INFLUENCE OF THE EXPLOITATION OF SIBAY DEPOSIT (THE SOUTHERN URALS) ON THE TRANSFORMATION OF METAL MIGRATION IN SUBORDINATE LANDSCAPES

Abstract

The regularities of migration and accumulation of heavy metals in geochemical conjugations under mining technogenic conditions were studied. The case study examines mining and milling of copper-zinc ore deposits in Sibay (the South Urals region). Landscapes in the valley of the Karagaily River, the Southern Urals, have been the objects of investigation since 2004. Soils and vegetation of the watershed, river water, bottom sediments and mine wastewater entering the watercourse were investigated, and the role of technogenic and artificial geochemical barriers was estimated. It is found that mining industry causes significant contamination of natural environment with Cu, Zn, Cd, Fe and Pb. Water bodies occupying the lowest level in geochemical interactions experience the maximum load. On the average the concentrations of Cu, Zn and Cd in dispersion flow (water, bottom sediments) are by two orders of magnitude higher than their percentage abundances. Migration and accumulation of metals are governed by technogenic physical and chemical barriers, among which the alkaline and sorption ones play the leading role. Heavy metal concentrations in biomass, coastal aquatic and terrestrial vegetation were found. Low values of the coefficient of biological absorption by plants compared to the background were revealed. We concluded that plants act as a certain phyto-barrier stabilizing the technogenic flow of substances and reducing the intensity of pollutants consumption by top organisms of the food chain. The violation of interdependence of substance flows in subordinate landscapes and the lack of correlation between concentrations of metals in soil-forming rocks, soil, plants, water and bottom sediments are also shown.

 

About the Authors

A. Y. Opekunov
Saint-Petersburg State University, Institute of Earth Sciences
Russian Federation
Department of Geoecology and Environmental Management, Professor, D.Sc. in Geology and Mineralogy


M. G. Opekunova
Saint-Petersburg State University, Institute of Earth Sciences
Russian Federation

Department of Geoecology and Environmental Management, Professor,
D.Sc. in Geography



V. V. Somov
Saint-Petersburg State University, Institute of Earth Sciences
Russian Federation

Department of Geoecology and Environmental Management, postgraduate
student



E. S. Mitrofanova
Saint-Petersburg ecological company
Russian Federation
Management Engineer


S. Y. Kukushkin
Saint-Petersburg State University, Institute of Earth Sciences
Russian Federation
Department of Geoecology and Environmental Management, Senior Lecturer


References

1. Alibaeva L.G., Kulagin A.Ju. Ocenka urovnya zagryazneniya tyazhelymi metallami allyuvial’nyh pochv rek Bashkirskogo Zaural’ya [Assessment of the level of heavy metals pollution of alluvial soils of the rivers of the Bashkir Trans-Urals] // Vestnik Udmurtskogo universiteta. Biologiya, Nauki o Zemle. 2012. Vyp. 2.P. 3–9 (in Russian).

2. Baron S., Carignan J., Ploquin A. Dispersion of heavy metals (metalloids) in soils from 800-year-old pollution (Mont-Lozere, France) // Environ. Sci. Technol. 2006. V. 40. P. 5319–5326.

3. Elpat’evskij P.V. Geohimiya migracionnyh potokov v prirodnyh i prirodno-tehnogennyh geosistemah [Geochemistry ofmigration flows in natural and natural-anthropogenic geosystems]M.: Nauka, 1993. 253 p. (in Russian).

4. Emlin Je.F. Prikladnaya geohimiya. Migraciya cinka i kadmiya v geotehnogennyh sistemah sul’fofil’nogo ryada. [Applied Geochemistry. Migration of zinc and cadmium in geo-technogenic systems of sulfophilous series] Textbook. Ekaterinburg: Izd-vo UGGU, 2005. 97 p. (in Russian).

5. Geohimiya landshaftov i geografiya pochv. 100 let so dnya rozhdeniya M.A. Glazovskoj [Landscape Geochemistry and Soil Geography. Centenary of the birth of M.A. Glazovskaya] / Pod red. N.S. Kasimovа, M.I. Gerasimovoj. M.: APR, 2012. 600 p. (in Russian).

6. Glazovskaya M.A. Geohimicheskie bar’ery v pochvah ravnin: tipologiya, funkcional’nye osobennosti i ekologicheskoe znachenie [Geochemical barriers in the soils of plains: typology, functional features and environmental significance] // Vestnik Mosk. un-ta. Ser. 5: Geografija. 2012. № 1. P. 8–14 (in Russian).

7. Glazovskaya M.A. Geohimiya prirodnyh i tehnogennyh landshaftov [Geochemistry of natural and technogenic landscapes].M.: Vysshaya shkola, 1988. 328 p. (in Russian).

8. IUSS Working Group WRB. World reference base for soil resources 2014, update 2015. International soil classification system for naming soils and creating legends for soil maps. Word Soil Resources Report 106. FAO. Rome. 2015.

9. Kabata-Pendias A., Mukherjee A.B. Trace elements from soil to human. Springer, Berlin, Heidelberg, New York, Germany, U.S., 2007. 550 p.

10. Kosarev A.M., Puchkov V.N., Seravkin I.B. Petrologogeohimicheskie osobennosti srednedevonsko-kamennougol’nyh ostrovoduzhnyh i kollizionnyh vulkanitov Magnitigorskoj zony v geodinamicheskom kontekste [Petrological and geochemical features of the Early Devonian-Eifelian island-arc and collisional volcanites of the Magnitogorsk zone in the geodynamic context] // Litosfera. 2006. № 4. P. 3–21 (in Russian).

11. Kosheleva N.E., Kasimov N.S., Bazha S.N., Gunin P.D., Golovanov D.L., Yamnova I.A., Jenhamgalan S. Zagryaznenie pochv tyazhelymi metallami v promyshlennyh gorodah Mongolii [Pollution of soils with heavy metals in the industrial cities of Mongolia] Vestnik Mosk. un-ta. Ser. 5: Geografiya. 2010. №3. P. 20– 27 (in Russian).

12. Koval’skij V.V., Krivitskij V.A., Alekseeva S.A., Letunova S.V., Opekunova M.G., Skarlygina-Ufimtseva M.D., Berman Sh., Ilzin’ A., Peterson N., Zhogova E.P., Rublik R.Ya. Yuzhno-Ural’skij subregion biosfery [The Southern Urals subregion of the biosphere] // Tr. biogeokhim. lab. 1981. T. 19. P. 3–64 (in Russian).

13. Kulagin A.Yu., Kutliahmetov A.N., Dorozhkin E.M., Kolesnikova A.M. Tehnogennoe zagryaznenie rek Bashkirskogo Zaural’ya [Technogenic pollution of rivers in the Bashkir Trans-Urals]// Prirodnoe nasledie Rossii v 21-m veke. Vtoraya mezhdunarodnaya nauchno-prakticheskaya konferenciya, 2008.P. 230–234 (in Russian).

14. Liu L., Wu L., Luo Y., Zhang C., Jiang Y., Qiu X. The impactof a copper smelter on adjacent soil zinc and cadmium fractions and soil organic carbon // J. the Soils and Sediments. 2010. V. 10. № 5.P. 808–817.

15. Opekunov A.Yu., Leont’eva L.V., Kuprina M.S. Geohimicheskie osobennosti sovremennogo osadkoobrazovaniya v rajone razrabotki Sibajskogo mednokolchedannogo mestorozhdeniya (Juzhnyj Ural). [Geochemical features of modern sedimentation in the development area of Sibay massive sulfide deposit (Southern Urals)] // Vest. S.-Peterb. un-ta. 2010. Ser. 7. Vyp. 2. (№ 15). P. 84–98 (in Russian).

16. Opekunov A.Yu., Mitrofanova E.S. Migraciya tyazhelyh

17. metallov v tehnogennyh potokah rasseyaniya Sibajskogo mednokolchedannogo mestorozhdeniya [Migration of heavy metals in technogenic dispersal flows of the Sibay massive sulfide deposit] Geohimiya landshaftov (k stoletiyu A.I. Perel’mana) // Dokl. Vseross. nauchn. konf. Moskva 18–20 oktyabrya 2016 g. Geograficheskij f-t MGU, 2016. P. 53–57 (in Russian).

18. Opekunov A.Yu., Opekunova M.G. Geokhimiya tekhnogeneza v rayone razrabotki Sibayskogo medno-kolchedannogo mestorozhdeniya // [Geochemistry of technogenesis in the area of the Sibay massive sulfide deposit development] Zapiski Gornogo instituna. T. 203. 2013. P. 196–204 (in Russian).

19. Opekunov A.Yu., Opekunova M.G., Somov V.V. Osobennosti migracii i akkumulyacii tyazhelyh metallov v geosisteme oz. Kultuban (Yuzhnyj Ural). [Specific features of migration and accumulation of heavy metals in the ecosystem of the Kultuban Lake (the Southern Urals)] // Mezhdunarodnyj nauchno-issledovatel’skij zhurnal. 2017. № 2. P. 52–55 (in Russian).

20. Opekunova M.G. Diagnostika tehnogennoj transformacii landshaftov na osnove bioindikacii [Diagnostics of the anthropogenic transformation of landscapes on the basis of bioindication.]. Diss. dok. geogr. nauk: 25.00.23: zashhishhena 05.03.13 : utv. 10.02.14. SPb.: Sankt-Peterburgskij gos. un-t., 2013. 402 p. (in Russian).

21. Opekunova M.G., Somov V.V., Papyan E.E. Soil Contamination in the Impact Zone of Mining Enterprises in the Bashkir Transural Region // Eurasian Soil Science. 2017. V. 50. № 6. P. 732–745. DOI:10.1134/S1064229317060084

22. Perel’man A.I., Kasimov N.S. Geohimiya landshafta [Landscape Geochemistry]. M.: Astreya-2000, 1999. 610 p. (in Russian).

23. Rafikova Yu.S., Semenova I.N. Othody gornorudnogo proizvodstva i soderzhanie metallov v okruzhayushhej srede [Mining wastes and metal concentrations in the environment] // Mezhdunarodnyj zhurnal prikladnyh i fundamental’nyh issledovanij. 2010. № 9. P. 73–74 (in Russian).

24. Regiony i goroda Rossii: integral’naja ocenka ekologicheskogo sostoyaniya [Regions and cities of Russia: an integrated assessment of the environmental condition] / Pod red. N.S. Kasimova. M.: IP Filimonov M.V., 2014. 560 p.

25. Schlesinger W.H., Bernhardt E.S. Biogeochemistry: An analysis of global change. 3-rd edition. Elsevier, 2013. 688 p.

26. Shoba V.N., Karpov I.K. Fiziko-himicheskoe modelirovanie v pochvovedenii [Physical-chemical modeling in the soil science]. Novosibirsk: RPO SO RASHN, 2004. 180 p. (in Russian).

27. Siegel F.R. Environmental geochemistry of potentially toxic metals. Springer-Verlag, Berlin, 2002. 218 p.

28. Timofeev I.V., Kosheleva N.E. Geochemical disturbance of soil cover in the nonferrous mining centers of the Selenga River basin // Environ. Geochem. Health. 2017. V. 39. P. 803–819. DOI:10.1007/ s10653-016-9850-0.

29. Timofeev I.V., Kosheleva N.E., Kasimov N.S. et al. Geochemical transformation of soil cover in copper – molybdenum mining areas (Erdenet, Mongolia) // J. Soil Sediments. 2016. V. 16. P. 1225–1237. DOI: 10.1007/s11368-015-1126-2.

30. Vodyanickij Yu.N. Zagryaznenie pochv tyazhelymi metallami i metalloidami i ih ekologicheskaya opasnost’ (analiticheskij obzor) [Pollution of soils with heavy metals and metalloids and their environmental hazard (analytical review)] // Pochvovedenie. 2013. № 7. P. 872–881 (in Russian).

31. Vostroknutov G.A. Sovremennye komp’yuternye tehnologii geohimicheskogo prognozirovaniya [Modern computer technologies of geochemical forecasting] // Prikladnaya geohimiya. M.: IMGRE, 2002. Vyp. 3. P. 287–304 (in Russian).


Review

For citations:


Opekunov A.Y., Opekunova M.G., Somov V.V., Mitrofanova E.S., Kukushkin S.Y. INFLUENCE OF THE EXPLOITATION OF SIBAY DEPOSIT (THE SOUTHERN URALS) ON THE TRANSFORMATION OF METAL MIGRATION IN SUBORDINATE LANDSCAPES. Vestnik Moskovskogo universiteta. Seriya 5, Geografiya. 2018;1(1):14-24. (In Russ.)

Views: 1101


Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.


ISSN 0579-9414 (Print)