Geochemical features of alluvial soils of the middle reaches of the Bolshaya Kokshaga river
https://doi.org/10.55959/MSU0579-9414.5.79.5.3
Abstract
The article presents the results of work on the identification of the paragenesis of chemical elements and radial geochemical barriers in the basic alluvial soils (Fluvisols) of the middle reaches of the Bolshaya Kokshaga River (Republic of Mari El). It was found that the leading (typomorphic) element is Fe, with which Mn, Ba, P, Zn and Ni are associated. Al forms a geochemical family with K, Mg, Ti and Cr. The content of Ca, S, Sr and Cu is related to the amount of loss during calcination, and Na and Zr are related to Si. Particular elements are fixed on radial geochemical barriers: Si and Zr on the mechanical, Ca, S, Sr and Cu on the biogeochemical, Al, K, Mg, Ti and Cr on the sorption, Fe on the oxygen and Mn, Ba, P, Zn and Ni on the chemisorptions one. The peak concentrations of Si and Zr were recorded on mechanical barrier in the profile of all types of soils. Ca, S, Cu and Sr are fixed on the biogeochemical barrier in turf and swamp soils. Increased concentrations of Al, K, Mg, Ti and Cr were found on the sorption barrier in all types of soils. The effect of oxygen and chemisorption barriers reveals itself in meadow and humus-gley soils.
About the Authors
A. V. Isaev
State Nature Reserve “Bolshaya Kokshaga”
Russian Federation
Russian Federation
Deputy Director for Scientifi c Department, Ph.D. in Agriculture
Y. P. Demakov
State Nature Reserve “Bolshaya Kokshaga”
Russian Federation
Russian Federation
Chief Scientifi c Researcher, D.Sc. in Biology
R. N. Sharafutdinov
Naberezhnye Chelny Institute of Kazan (Volga Region) Federal University
Russian Federation
Russian Federation
Department of Chemistry and Ecology, Associate Professor, Ph.D. in Biology
L. V. Ryzhova
State Nature Reserve “Bolshaya Kokshaga”; Mari State University, Institute of Natural Sciences and Pharmacy
Russian Federation
Russian Federation
Department of Biology, Associate Professor, Ph.D. in Biology
References
1. Aristovskaja T.V. Mikrobiologija processov pochvoobrazovanija [Microbiology of soil formation processes], Leningrad, Nauka Publ., 1980, 187 p. (In Russian)
2. Barrón V., Torrent J. Iron, manganese and aluminium oxides and oxyhydroxides, European Mineralogical Union Notes in Mineralogy. Notes in Mineralogy, 2013, vol. 14, ch. 9, p. 297–336, DOI: 10.1180/EMU-notes.14.9.
3. Dobrovol’skij G.V. Pochvy rechnyh pojm centra Russkoj ravniny [Soils of river floodplains in the center of the Russian Plain], Moscow, Moscow St. Univ. Publ., 2005, 293 p. (In Russian)
4. Dobrovol’skij V.V. Biosphere cycles of heavy metals and regulatory role of soil, Eurasian Soil Science. 1997, no. 4, p. 371–380.
5. Enang R.K., Kfuban Yerima B.P., Kome G.K., Rans E.V. Trace elemental distribution in tephra soils of mounts Kupe and Manengouba (Cameroon), Eurasian Soil Science, 2020, no. 5, p. 595–606, DOI: 10.1134/s1064229320050051.
6. Gavrilenko V.V., Sahonenok V.V. Osnovy geohimii redkih litofil’nyh metallov [Fundamentals of geochemistry of rare lithophilic metals], Leningrad, Leningrad St. Univ. Publ., 1986, 172 p. (In Russian)
7. Geohimicheskie bar’ery v zone gipergeneza [Geochemical barriers in the hypergenesis zone], N.S. Kasimov, A.E. Vorob’jov (еds.), Moscow, Moscow St. Univ. Publ., 2002, 395 p. (In Russian)
8. Glazovskaja M.A. Geohimicheskie bar’ery v pochvah ravnin, ih tipologija, funkcional’nye osobennosti i jekologicheskoe znachenie [Geochemical barriers in plains soils, their typology, functional features and ecological significance], Lomonosov Geography Journal, 2012,no. 1, p. 8–14. (In Russian)
9. Haruna I.V., Ishaku J.M., Mamman Y.D. Background Geochemistry of Soil in Part of Girei District, Upper Benue Trough, N. E. Nigeria, International Journal of Geosciences, 2017, no. 8, p. 888–901, DOI: 10.4236/ ijg.2017.87051.
10. Isaev A.V. Formirovanie pochvennogo i rastitel’nogo pokrova v pojmah rechnyh dolin Marijskogo Poles’ja (na primere territorii zapovednika “Bol’shaja Kokshaga”) [Formation of soil and vegetation cover in floodplains of river valleys of the Mari Polesie (case study of the territory of the “Bolshaya Kokshaga” reserve)], Joshkar-Ola, Mari St. Technical Univ. Publ., 2008, 240 p. (In Russian)
11. Isaev A.V., Demakov Ju.P., Sharafutdinov R.N. Zakonomernosti izmenenija granulometricheskogo sostava alljuvial’nyh pochv v processe razvitija pojm rek [Regularities of changes in the granulometric composition of alluvial soils during the development of flood-plains], Vestnik Povolzhskogo gos. tehn. un-ta, Ser. Les. Ekologija. Prirodopol’zovanie, 2022, no. 2, p. 80–93, DOI: 10.25686/2306-2827.2022.2.80. (In Russian)
12. Isaev A.V., Demakov Y.P., Sharafutdinov R.N. Specific Fea tures of the Elemental Composition of Alluvial Soils in the Middle Reaches of the Bolshaya Kokshaga River Eurasian Soil Science, 2023, vol. 56, no. 7, p. 868–878, DOI: 10.1134/S1064229323600653.
13. Isaev A.V., Sharafutdinov R.N., Gareev B.I. Ekologo-geohimicheskaja harakteristika alljuvial’nyh otlozhenij v srednej chasti r. Bol’shaja Kokshaga i ih rol’ v formirovanii pochvennogo pokrova [Ecological and geochemical characteristics of alluvial deposits in the middle part of the Bolshaya Kokshaga River and their role in the formation of soil cover], Nauch. tr. gos. prirodnogo zapovednika “Bol’shaja Kokshaga”, 2020, iss. 9, p. 8–29. (In Russian)
14. Judovich Ja.Je., Ketris M.P. Geohimija marganca v processah gipergeneza: obzor [Geochemistry of manganese in hypergenesis processes: an overview], Biosfera, 2013, vol. 5, no. 1, p. 21–36. (In Russian)
15. Kasimov N.S., Lychagin M.Ju., Chalov S.R., Shinkareva G.L. Parageneticheskie associacii himicheskih jelementov v landshaftah [Paragenetic associations of chemical elements in landscapes], Lomonosov Geography Journal, 2019, no. 6, p. 20–28. (In Russian)
16. Klassifikacija i diagnostika pochv SSSR [Classification and diagnostics of soils of the USSR], Moscow, Kolos Publ., 1977, 224 p. (In Russian)
17. Kolevatyh E.A. K voprosu o genezise i geohimii pokrovnyh suglinkov Vjatsko-Kamskogo Predural’ja [On the genesis and geochemistry of the cover loams of the Vyatka-Kama Pre-Urals], Litosfera, 2010, no. 6, p. 55– 65. (In Russian)
18. Kosheleva N.E., Kasimov N.S., Vlasov D.V. Impact of Geochemical Barriers on the Accumulation of Heavy Metals in Urban Soils, Doklady Earth Sciences, 2014, vol. 458, рt. 1, p. 1149–1153, DOI: 10.1134/S1028334X14090165.
19. Kovda V.A. Biogeohimija pochvennogo pokrova [Biogeochemistry of soil cover], Moscow, Nauka Publ., 1985, 264 p. (In Russian)
20. Michael A.W., Allyson V.Y., Bruce D.K. et al. Geochemistry of Alluvial Soils Composed of Metal-Enriched Sediments, Main Stem of the Coeur d’Alene River, Idaho, Soil Science Society of America Journal Abstract – Soil Mineralogy, 2012, vol. 76, no. 4, p. 1462–1477, DOI: 10.2136/sssaj2011.0442.
21. Mаnceau A., Marcus M.A., Tamura N. Quantative speciation of heavy metals in soils and sediments by synchrotron X ray techniques, Applications of Synchrotron Radiation in Low-Temperature Geochemistry and Environmental Science, Reviews in Mineralogy and Geochemistry, 2002, vol. 49, p. 341–428, DOI: 10.2138/gsrmg.49.1.341.
22. Perel’man A.I., Kasimov N.S. Geohimija landshafta [Geochemistry of the landscape], Moscow, Astreja-2000 Publ., 1999, 768 p. (In Russian)
23. Smirnov V.N. Pochvy Marijskoj ASSR, ih genezis, jevoljucija i puti uluchshenija [Soils of the Mari ASSR, their genesis, evolution and ways of improvement], Joshkar-Ola, Marijsk. kn. izd-vo Publ., 1968, 532 p. (In Russian)
24. Sysuev V.V. Formation Processes and Parameters of the Landscape–Geochemical Barrier of the Eutrophic Swamp, Geochemistry International, 2021, vol. 59(7), p. 699–710, DOI: 10.1134/S0016702921060100.
25. Vasil’ev A.A., Romanova A.V. Zhelezo i tjazhelye metally v alljuvial’nyh pochvah Srednego Predural’ja [Iron and heavy metals in alluvial soils of the Middle Urals], Perm, Prokrost Publ., 2014, 231 p. (In Russian)
26. Vasil’eva D.P. Landshaftnaja geografija Marijskoj ASSR [Landscape geography of the Mari ASSR], Joshkar-Ola, Marijsk. kn. izd-vo Publ., 1979, 136 p. (In Russian)
27. Vlasov D.V., Kasimov N.S. Geohimicheskie anomalii metallov i metalloidov v komponentah landshaftov v vostochnoj chasti Moskvy: paragenezisy jelementov i tipologija [Geochemical anomalies of metals and metalloids in landscape components in the Eastern part of Moscow: paragenesis of elements and typology], Lomonosov Geography Journal, 2016, no. 3, p. 50–57. (In Russian)
28. Vodjanickij Ju.N. Srodstvo tjazhelyh metallov i metalloidov k fazam-nositeljam v pochvah [Affinity of heavy metals and metalloids to carrier phases in soils], Agrohimija, 2008, no. 9, p. 87–94. (In Russian)
29. Vodjanickij Ju.N., Vasil’ev A.A., Vlasov M.N. Hydrogenic heavy metal pollution of alluvial soils in the city of Perm, Eurasian Soil Science, 2008, no. 11, p. 1238–1246.
30. Vodjanickij Ju.N., Vasil’ev A.A., Vlasov M.N., Korovushkin V.V. The role of iron compounds in fixing heavy metals and arsenic in alluvial and soddy-podzolic soils in the Perm area, Eurasian Soil Science, 2009, no. 7, p. 738–749.
Review
For citations:
Isaev A.V., Demakov Y.P., Sharafutdinov R.N., Ryzhova L.V. Geochemical features of alluvial soils of the middle reaches of the Bolshaya Kokshaga river. Lomonosov Geography Journal. 2024;(5):27-39. (In Russ.) https://doi.org/10.55959/MSU0579-9414.5.79.5.3
Views:
104
Email this article 
